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020 _a9780429783845
_q(electronic bk.)
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035 _a(OCoLC)1057341437
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035 _a(OCoLC-P)1057341437
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245 0 0 _aModern electrosynthetic methods in organic chemistry /
_cedited by Frank Marken and Mahito Atobe.
264 1 _aBoca Raton :
_bCRC Press,
_c2018.
300 _a1 online resource :
_bcolor illustrations.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
490 1 _aNew Directions in Organic & Biological Chemistry
505 0 _aCover; Half Title; Series Page; Title Page; Copyright Page; Contents; Preface; Editors; Contributors; Chapter 1 Introduction to Practical Methods in Electroorganic Syntheses; 1.1 Introduction to Electrosynthetic Methods; 1.1.1 Approaching Electroorganic Synthesis; 1.1.2 Mass Transport; 1.1.2.1 Mass Transport and Computational Mechanistic Tools; 1.1.3 Solvents and Electrolytes; 1.1.3.1 Organic Solvents; 1.1.3.2 Ionic Liquids; 1.1.3.3 Polymer Solvents; 1.2 Methodology for Direct Transformations; 1.2.1 Anodic Processes; 1.2.2 Cathodic Processes.
505 8 _a1.3 Methodology for Indirect and Catalytic Transformations1.3.1 Anodic Processes; 1.3.2 Cathodic Processes; 1.4 Methodology for Paired Transformations; 1.5 Outlook, Conclusions, and Recommendations; References; Chapter 2 Cogeneration Electrosynthesis; 2.1 Introduction; 2.2 Electricity and Chemical Cogeneration Processes; 2.2.1 Introduction to Cogeneration; 2.2.2 Chemical Cogeneration in Aqueous Electrolyte Fuel Cells; 2.2.3 Chemical Cogeneration in Aqueous Phosphorous Acid Fuel Cells; 2.2.4 Chemical Cogeneration in Polymer Electrolyte Fuel Cells.
505 8 _a2.2.5 Chemical Cogeneration in Solid Oxide Fuel Cells2.2.6 Chemical Cogeneration in Molten Salt Fuel Cells; 2.3 Conclusion; References; Chapter 3 Photoelectrochemically Driven Electrosynthesis; 3.1 Introduction to Photoelectrochemistry; 3.2 Advantages of Light-Assisted Electrosynthesis in Mediator System; 3.3 Light-Assisted Electrosynthesis by Natural Cobalamin Derivative; 3.4 Light-Assisted Electrosynthesis by Vitamin B[sub(12)] Derivatives; 3.5 Light-Assisted Electrosynthesis by Simple Vitamin B[sub(12)] Model Complex; 3.6 Outer or Inner Photovoltaic Device Systems; 3.7 Concluding Remarks.
505 8 _a5.2 Cathodic Conversions at Boron-Doped Diamond Electrodes5.2.1 Carbon Dioxide Reduction; 5.2.2 Cathodic Reductive Coupling of Methyl Cinnamates; 5.2.3 Reduction of Oximes; 5.3 Anodic Transformations at Boron-Doped Diamond Electrodes; 5.3.1 Alkoxylation Reactions; 5.3.2 Fluorination; 5.3.3 Cyanation; 5.3.4 Cleavage of C, C-Bonds; 5.3.5 Electrochemical Amination Reactions; 5.3.6 Anodic Phenol Coupling Reaction; 5.4 Novel Concepts and Electrode Materials for Electrochemical Reductions; 5.4.1 Improvement of Existing Cathodes; 5.4.2 Novel Cathode Materials; 5.5 Summary; References.
520 _aModern Electrosynthetic Methods in Organic Chemistry introduces readers to new ways of making materials and compounds using low waste processes, employing energy from electricity rather than chemical reagents. It explores electro-organic synthesis, which offers clean synthesis tools as well as unusual reaction intermediates and reaction types. Despite applications previously remaining niche, due to the advent of microfluidic reactors this book is a must-read for industry professionals and academics alike. It targets specific areas of recent progress and development in the field that show high novelty and potential, at the same time inviting a wider range of applications in green and clean technology.
588 _aOCLC-licensed vendor bibliographic record.
650 0 _aOrganic compounds
_xSynthesis.
650 0 _aElectrochemistry.
650 0 _aChemistry, Physical and theoretical.
650 7 _aSCIENCE
_xChemistry
_xOrganic.
_2bisacsh
700 1 _aAtobe, Mahito,
_d1969-
_eeditor.
700 1 _aMarken, Frank,
_eeditor.
856 4 0 _3Read Online
_uhttps://www.taylorfrancis.com/books/9780429434051
856 4 2 _3OCLC metadata license agreement
_uhttp://www.oclc.org/content/dam/oclc/forms/terms/vbrl-201703.pdf
942 _2lcc
_cEBK
999 _c17582
_d17582